南秦岭石泉-汉阴北部煌斑岩脉特征及与金矿化的关系

羊坪湾矿区位于南秦岭南部逆冲推覆系迎丰-搁河口推覆体。北邻留凤关-金鸡岭褶皱束,西邻扬子准地台汉南凸起,南接北大巴山弧形褶皱带。矿区出露地层由南西向北东依次为洞河群（Z2-O）和下志留统梅子垭组（S1m）。其中洞河群分布于矿区的西南部,呈北西向展布,总体北东倾,倾角15°～45°,主要为硅质板岩,板岩中局部夹薄层炭质绢云石英片岩。下志留统梅子垭组倾向北东,倾角一般15°～50°,局部倾角最高可达75o,地层沿倾向及走向具波状起伏特征。梅子垭组以绢云石英片岩、二云石英片岩、含炭绢云石英片岩为主,以及夹有少量灰岩、大理岩条带等。金矿均赋存于志留系梅子垭组二云母石英片岩和含炭二云石英片岩中,以前者为主,约占90%以上。黄龙金矿区出露地层为下志留统梅子垭组,岩性为一套巨厚的浅变质细碎屑岩系,主要为绢云石英片岩、变砂岩、含黑云母变斑晶绢云石英片岩、含炭绢云石英片岩、含石榴子石黑云母变斑晶绢云石英片岩等。其中与矿（化）体关系最为密切的岩性为含炭绢云石英片岩、含黑云母变斑晶绢云石英片岩、含石榴子石黑云母变斑晶绢云石英片岩。     

近54年阿勒泰地区夏季极端降水事件气候特征

本文采用阿勒泰地区7个国家级气象站近54a(1960～2013年)夏季(6～8月)的日有效降水量（20～20h降水量≥0.1mm）资料,用WMO推荐的百分位法计算了全地区过去54a夏季极端强降水的阈值、进一步分析了当地夏季时空分布特征及变化趋势,结果表明：阿勒泰地区夏季极端强降水阈值呈西部、南部小,北部、东部大,并且空间异常分布特征如下: 夏季以及夏季各月的极端强降水日数和强度均可总结出5种最主要模型;极端强降水量可总结出8种最主要模型;并且通过时间标准化序列分析各种模型都有对应的降水日数、量级、强度明显偏多（强）和偏少（弱）的时段。日数、量级、强度近54a来,除吉木乃略有下降以外,其余各县（市）均为增长趋势,尤其是北部、东部地区.同时上述三指标存在着显著的年代际和年纪尺度的周期变化,上世纪90年代和2010年至今为三个指标最多(强)的年代,而上世纪70年代为最少（最差）的年代.并通过周期分析（小波分析）可知,均有对应的显著变化周期。     

基于层区带刻度区地质特点的资源评价方法适用性分析

针对新型的层区带刻度区进行资源评价方法的适应性研究是长庆四次资评一项重要内容。采用油藏规模序列法、油藏过程模型法、容积法和饱和探井法4种资源评价方法,对具不同成藏特点的刻度区进行了深入的方法适用性分析和参数研究。研究结果表明,过程类资源评价方法对低渗透、特低渗透连续性岩性油藏,在以储量提交单元作为统计单元进行油藏发现序列与规模序列模拟时,计算参数的合理性与计算结果认知度很难达到统一。而勘探程度类资源评价方法,在深入的地质分析基础上,选择合理适宜的关键参数,是可以求得较为可信的地质资源量。当然,评价者对评价对象的认识程度和对评价方法的掌握程度也影响着资源评价的结果。     

降水井改造为原位生产井的工艺设计及应用

为有效地扩大油页岩原位开采区域和节约油页岩原位开采的成本,需将废置的降水井改造成为原位生产井。根据降水井与原位生产井井身结构的相似性,对农安油页岩原位开采先导试验工程基地的降水井改造工艺进行了设计和优化。同时研发了偏心轮式套管割管装置及三爪式套管打捞装置用于拔管施工。工程实践证明,该工艺具有步骤简单、合理、高效以及价格低廉等特点。偏心轮式套管割管装置及三爪式套管打捞装置应用在降水井改造中,均取得理想的效果。     

Using Geomechanical Method to Predict Tectonic Fractures in Low-Permeability Sandstone Reservoirs

Understanding and interpreting the timing, location, orientation, and intensity of natural fractures within a geological structure are commonly important to both exploration and production planning activities of low-porosity and low-permeability carbonate reservoirs. In this study, we explore the application of comprehensive geomechanical methods to quantitatively characterize the fracture parameters based on Strain Energy Density Theory, such as linear fracture density and volume fracture density. This study approach is based on the idea that energy generated by tectonic stress on brittle sandstone,which can be distinguished fracture surface energy, friction energy dissipation and residual strain energy and natural fractures can be interpreted or inferred from geomechanical-model-derived strains. For this analysis, we model an extension and compression compound fault block developed in a mechanically stratified sandstone and shale sequence because mechanics experimental data and drilling data exist that can be directly compared with model results.However, the results show that the approach and our study conclusion are independent of the specified structural geometry, which can correlate fracture parameters in different stages with different tectonic activities, and finally build and visualize fracture networks in sandstone. The presence or absence of filling minerals in fractures is shown to strongly control the destruction and transformation of low-permeability sandstone, and this control possesses crucial implications for interpreting fracture aperture and reservoir flow simulation.     

高压下天然菱铁矿的压缩性和电子结构研究

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。     

仿生高效切削齿试验研究

在仿生高效耐磨理论的指导下,以鼹鼠爪趾为仿生原型,引入了其经长期进化而具有的高效、耐磨的特性。选用CVD多晶金刚石为切削齿的切削单元,采用真空热压烧结工艺制备仿生高效切削齿,并将其与常规PDC齿、仿生PDC齿的耐磨性和切削效率进行对比试验,结果显示：仿生高效切削齿的耐磨性较常规PDC齿提高23%;切削效率较常规PDC齿提高1.49倍,较仿生PDC齿提高48%。初步证明了仿生高效切削齿工艺的可行性,为下一步高效切削钻头的研究奠定了坚实的基础。     

Antialgal and antilarval activities of bioactive compounds extracted from the marine dinoflagellate <Emphasis Type="Italic">Amphidinium carterae</Emphasis>

With the global ban on the application of organotin-based marine coatings by the International Maritime Organization, the development of environmentally friendly, low-toxic and nontoxic antifouling compounds for marine industries has become an urgent need. Marine microorganisms have been considered as a potential source of natural antifoulants. In this study, the antifouling potential of marine dinoflagellate Amphidinium carterae, the toxic and red-tide microalgae, was investigated. We performed a series of operations to extract the bioactive substances from Amphidinium carterae and tested their antialgal and antilarval activities. The crude extract of Amphidinium carterae showed significant antialgal activity and the EC₅₀ value against Skeletonema costatum was 55.4 μg mL^?1. After purification, the isolated bioactive substances (the organic extract C) exhibited much higher antialgal and antilarval activities with EC₅₀ of 12.9 μg mL^?1 against Skeletonema costatum and LC₅₀ of 15.1 μg mL^?1 against Amphibalanus amphitrite larvae. Subsequently, IR, Q-TOFMS, and GC-MS were utilized for the structural elucidation of the bioactive compounds, and a series of unsaturated and saturated 16- to 22-carbon fatty acids were detected. The data suggested the bioactive compounds isolated from Amphidinium carterae exhibited a significant inhibiting effect against the diatom Skeletonema costatum and Amphibalanus amphitrite larvae, and could be substitutes for persistent, toxic antifouling compounds.     

黄铁矿ReOs法测年在胶东金矿中的应用初探

该次工作为黄铁矿Re-Os法测年在胶东金矿中的首次应用。在大尹格庄金矿中获得了由3件黄铁矿样品组成的(144.8±1.8)Ma等时线年龄,暗示着大尹格庄金矿区可能存在一期晚侏罗世的Au成矿事件。通过对大尹格庄、夏甸、土堆金矿黄铁矿Re-Os同位素年代学的研究,表明黄铁矿的Re-Os同位素特征在胶东金矿中具有一定的复杂性。该文总结了影响黄铁矿Re-Os同位素测年结果的因素,认为在利用该方法进行金矿床定年时,应当将不同期次黄铁矿分别送样,适当拉大采样间距,并尽可能降低实验测试误差,以期获得更精确可靠的年龄。